Cast iron and Matfer carbon steel are both coating-free, professional-grade cookware with essentially identical safety profiles — both rate 'best' because neither uses synthetic coatings of any kind. The seasoning on both is polymerized cooking oil, not a manufactured coating. Both leach trace dietary iron, which is nutritionally neutral or beneficial for most people. There is no meaningful safety distinction between the two materials.
The differences are performance-oriented. Cast iron is thicker, heavier, and retains heat longer — excellent for searing, baking, and dishes that benefit from sustained high heat. It heats more slowly and is less responsive to temperature changes. Matfer carbon steel is thinner, lighter, and heats more quickly and responsively — the professional kitchen choice for eggs, crepes, sauteed vegetables, and high-heat stovetop cooking where control matters.
Matfer's Blue Steel carbon steel requires careful initial seasoning — the factory coating must be boiled off, and the pan must be properly conditioned before use. Cast iron typically comes pre-seasoned and is ready to use sooner. Both require similar ongoing maintenance (drying thoroughly, light oiling). For households that cook frequently and want a versatile coating-free pan for stovetop work, Matfer carbon steel is the professional upgrade. For oven-to-stovetop work and heat retention, cast iron is unmatched. Either is an outstanding choice from a safety standpoint.